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The electrochemical equivalent of pure silver - a value of the Faraday

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Title	The electrochemical equivalent of pure silver - a value of the Faraday
Author	Bower, V.E.; Davis, R.S.
SeriesTitle	Journal of Research of the National Bureau of Standards
Date	1980-05
Language	English
Keywords	Coulometry; electrochemical equivalent; electrochemistry; Faraday; fundamental constants; silver.
Abstract	Oxygen-free high-purity samples were used in a precise determination of the electrochemical equivalent of silver. A comprehensive mass spectrometric analysis for impurities was performed. Our value agrees well with prior measurements of the same quantity at the National Bureau of Standards (NBS) by Craig and coworkers. We find the electrochemical equivalent of pure silver to be 1.1179648 mg C-1NBS. Attached to this figure is an uncertainty whose random component (standard deviation of the mean of 8 determinations) is 9.5 X 10-7 mg C-1 (0.85 ppm). The root-sum-square of systematic uncertainties of known origin is 1.07 X 10-6 mg C-1 (0.96 ppm). The above value for the electrochemical equivalent of silver leads us to calculate the Faraday to be: F = 96486.33 (24) ANBS s mol-1 (2.5 ppm).
Publisher	National Bureau of Standards
ISSN	0160-1741
Volume	85
Issue	3
Page	175
Cite	J. Res. Bur. Stand., Vol. 85, No. 3, p. 175
Rights	The Journal of Research of the National Institute of Standards and Technology is a publication of the U.S. Government. The papers are in the public domain and are not subject to copyright in the United States. However, please pay special attention to the individual works to make sure there are no copyright restrictions indicated. Individual works may require securing other permissions from the original copyright holder.

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